Proceedings of the 8th Russian-Chinese Symposium “Coal in the 21st Century: Mining, Processing, Safety"

Mechanochemical capture of carbon disulfide by magnesium-carbon composite

Authors
Liu Bogu, Zhang Qianqian, Liu Pei, Chen Haipeng, Yu Hao, Zhou Shixue
Corresponding Author
Liu Bogu
Available Online October 2016.
DOI
https://doi.org/10.2991/coal-16.2016.69How to use a DOI?
Keywords
Anthracite; Magnesium; Sulfur fixation; Mechanochemical
Abstract
This work is concerned with mechanochemical capture of carbon disulfide (CS2) by magnesium-carbon composite from ball-miling of Mg and carbonized anthracite. XRD analysis shows that cubic crystal MgS forms when milling time increases more than 1.0 h. The sulfur contents in composites from 0.5, 1.0, 1.5 and 2.0 h of milling are 1.35, 6.02, 9.62 and 11.69 wt%, respectively. With the extension of milling time, the particle size of Mg decreases, while crystallite size of MgS shows an increase trend. The crystallite size of MgS in the composites from 1.0, 1.5 and 2 h of milling are 95, 132 and 275 Å, respectively. FT-IR analysis shows that there are four absorption peaks at 1210, 1005, 906 and 764 cm-1, corresponding to the C-S bond absorption, are obvious, suggesting that the crystallitic carbon can deliver sulfur atoms during capture reaction. The mechanism of CS2 capture by composite is simulated by first-principles calculation, and the density of states and deformation charge density maps of CS2 adsorption on Mg(0001) suggest that the adsorption is chemisorption. This work can pave a new pathway for the absorption of CS2.
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Proceedings
8th Russian-Chinese Symposium “Coal in the 21st Century: Mining, Processing, Safety"
Part of series
Advances in Engineering Research
Publication Date
October 2016
ISBN
978-94-6252-233-6
ISSN
2352-5401
DOI
https://doi.org/10.2991/coal-16.2016.69How to use a DOI?
Open Access
This is an open access article distributed under the CC BY-NC license.

Cite this article

TY  - CONF
AU  - Liu Bogu
AU  - Zhang Qianqian
AU  - Liu Pei
AU  - Chen Haipeng
AU  - Yu Hao
AU  - Zhou Shixue
PY  - 2016/10
DA  - 2016/10
TI  - Mechanochemical capture of carbon disulfide by magnesium-carbon composite
BT  - 8th Russian-Chinese Symposium “Coal in the 21st Century: Mining, Processing, Safety"
PB  - Atlantis Press
SP  - 360
EP  - 364
SN  - 2352-5401
UR  - https://doi.org/10.2991/coal-16.2016.69
DO  - https://doi.org/10.2991/coal-16.2016.69
ID  - Bogu2016/10
ER  -