Proceedings of the 2nd International Conference on Modelling, Identification and Control

Hydrogenation of Phenol with Different Catalysts in Supercritical Alcohol

Authors
Kong Zhaoni, Zhang Jianping, Guan Qingqing, Gu Junjie
Corresponding Author
Kong Zhaoni
Available Online August 2015.
DOI
10.2991/mic-15.2015.46How to use a DOI?
Keywords
-Phenol; Hydrogenation; Supercritical alcohol.
Abstract

Pd/C, Ni/SiO2-Al2O3 and Ru/C were used for hydrogenation of phenol in supercritical alcohol system. The results indicate that Pd/C is an efficient catalyst for hydrogenation of phenol in supercritical alcohol system, over 80% phenol was removed at initial 40 min and cyclohexane, cyclohexanol and cyclohexanone are main products. Since products such as 2 - ethyl phenol, 4 - ethyl phenol, 2-methyl -5-isopropyl phenol and 1-methoxy-4-isopropyl benzene are produced with Ni/SiO2-Al2O3 and 2 - ethyl phenol and dibutyl phthalate are found with Ru/C, Ni/SiO2-Al2O3 and Ru/C are not effective catalysts for hydrogenation reaction in supercritical alcohol system. Those two catalysts increases the ethylation reaction dramatically, rather than hydrogenation reaction.

Copyright
© 2015, the Authors. Published by Atlantis Press.
Open Access
This is an open access article distributed under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).

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Volume Title
Proceedings of the 2nd International Conference on Modelling, Identification and Control
Series
Advances in Intelligent Systems Research
Publication Date
August 2015
ISBN
978-94-62520-99-8
ISSN
1951-6851
DOI
10.2991/mic-15.2015.46How to use a DOI?
Copyright
© 2015, the Authors. Published by Atlantis Press.
Open Access
This is an open access article distributed under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).

Cite this article

TY  - CONF
AU  - Kong Zhaoni
AU  - Zhang Jianping
AU  - Guan Qingqing
AU  - Gu Junjie
PY  - 2015/08
DA  - 2015/08
TI  - Hydrogenation of Phenol with Different Catalysts in Supercritical Alcohol
BT  - Proceedings of the 2nd International Conference on Modelling, Identification and Control
PB  - Atlantis Press
SP  - 205
EP  - 207
SN  - 1951-6851
UR  - https://doi.org/10.2991/mic-15.2015.46
DO  - 10.2991/mic-15.2015.46
ID  - Zhaoni2015/08
ER  -