Effects of Process Conditions on Hydrogen Production of Fe Complexes Catalyst in Noble-Metal-Free System

DOI

10.2991/icmse-16.2016.8How to use a DOI?

Keywords

Fe complexes; Process conditions; Hydrogen

Abstract

In this paper, Fe thiolate complexes Fe(phen)(pyS)2 (M) were synthesized, the properties of complexes were characterized by 1H-NMR and MS. The effects of reaction conditions on catalytic performance of catalyst M had been studied. The results of catalytic performance indicated that the optimal reaction conditions were that catalyst concentration was 5.00%, triethylamine was the suitable electron donor and the optimal riethylamine content was 5.00%. The maximum hydrogen yield was156.1æmol/h after reacted for 15 hours and the life of catalyst M was 41 h under the optimal reaction conditions.

Copyright

© 2016, the Authors. Published by Atlantis Press.

Open Access

This is an open access article distributed under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).

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TY  - CONF
AU  - Chuang Zhang
AU  - Da-Tian Fu
AU  - Xiu-Lan Cai
PY  - 2016/12
DA  - 2016/12
TI  - Effects of Process Conditions on Hydrogen Production of Fe Complexes Catalyst in Noble-Metal-Free System
BT  - Proceedings of the 4th 2016 International Conference on Material Science and Engineering (ICMSE 2016)
PB  - Atlantis Press
SP  - 42
EP  - 46
SN  - 2352-5401
UR  - https://doi.org/10.2991/icmse-16.2016.8
DO  - 10.2991/icmse-16.2016.8
ID  - Zhang2016/12
ER  -