Thiolate Complexes Catalyst in Noble-Metal-Free System for Light-driven Hydrogen Production

DOI

10.2991/icmse-16.2016.5How to use a DOI?

Keywords

Fe thiolate complexes; Photocatalysis; Hydrogen

Abstract

In this paper, Fe thiolate complexes Fe(phen(pyS)2 (M) were synthesized and the properties of complexes were characterized by 1H-NMR and MS. The effects of reaction conditions on performanceof Fe thiolate complexes Fe(phen(pyS)2had been studied. The results of catalytic performance implied thatwhen 2.0 mMfluorescein was used as photosensitizer, ethanol/water was used as solvent and its volume ratio ofethanol/water was1:1, catalyst M showed the highest catalytic performance and hydrogen production was 115.6 æmol/h after reacted for 15 h.

Copyright

© 2016, the Authors. Published by Atlantis Press.

Open Access

This is an open access article distributed under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).

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TY  - CONF
AU  - Guang-Yan Li
AU  - Da-Tian Fu
AU  - Xiu-Lan Cai
PY  - 2016/12
DA  - 2016/12
TI  - Thiolate Complexes Catalyst in Noble-Metal-Free System for Light-driven Hydrogen Production
BT  - Proceedings of the 4th 2016 International Conference on Material Science and Engineering (ICMSE 2016)
PB  - Atlantis Press
SP  - 25
EP  - 29
SN  - 2352-5401
UR  - https://doi.org/10.2991/icmse-16.2016.5
DO  - 10.2991/icmse-16.2016.5
ID  - Li2016/12
ER  -