Proceedings of the 10th Annual Meeting of Risk Analysis Council of China Association for Disaster Prevention (RAC 2022)

Chlorine Poisoning Risk Management Based on ALOHA Simulation

Authors
Minyan Li1, Jianchao Wang1, Qian Zhang1, Deyin Huang1, *
1Institute of Occupational Health, Tianjin Bohai Chemical Industry Group Co. Ltd, Tianjin, China
*Corresponding author. Email: huang_deyin@126.com
Corresponding Author
Deyin Huang
Available Online 21 July 2023.
DOI
10.2991/978-94-6463-194-4_47How to use a DOI?
Keywords
ALOHA; liquid chlorine leaks; incident simulation; risk assessment; risk management; emergency strategies
ABSTRACT

In this paper, based on the investigation report of a liquid chlorine leakage accident during filling operation, ALOHA software was used to simulate the indoor and outdoor chlorine gas diffusion in different accident scenarios, and the emergency evacuation area was divided according to the different toxicity levels. A four-step method for risk assessment was used to identify the occupational hazards of liquid chlorine leakage in the process of liquid chlorine filling. The dose-response model of acute chlorine poisoning was selected to characterize the individual risks of different exposure concentrations and exposure durations. Different measures were taken to manage the risks depending on whether they were tolerable. It was verified that according to the accident investigation report information, the chlorine gas diffusion simulated by ALOHA were basically consistent with the actual casualties of personnel in the two surrounding companies. The concentration of chlorine gas in buildings with low ventilation rate was much lower than that outdoors. The risk for individual exposed to 235mg/m3 chlorine for less than 10 minutes, to 136mg/m3 chlorine for less than 30 minutes, or to 96mg/m3 chlorine for less than 60 minutes is tolerable. Risk management strategies vary depending on whether the risk is tolerable. The diffusion simulation results based on ALOHA have guiding significance for selecting the locations of crowded places in plant area, chemical industrial park and surrounding enterprises. In case of accident leakage, people in the downwind area to which poison gas has spread should first evacuate to the vertical wind direction and then escape to the upwind direction. If there is no respiratory protection, they should close the doors and windows and wait for rescue.

Copyright
© 2023 The Author(s)
Open Access
Open Access This chapter is licensed under the terms of the Creative Commons Attribution-NonCommercial 4.0 International License (http://creativecommons.org/licenses/by-nc/4.0/), which permits any noncommercial use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license and indicate if changes were made.

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Volume Title
Proceedings of the 10th Annual Meeting of Risk Analysis Council of China Association for Disaster Prevention (RAC 2022)
Series
Advances in Economics, Business and Management Research
Publication Date
21 July 2023
ISBN
10.2991/978-94-6463-194-4_47
ISSN
2352-5428
DOI
10.2991/978-94-6463-194-4_47How to use a DOI?
Copyright
© 2023 The Author(s)
Open Access
Open Access This chapter is licensed under the terms of the Creative Commons Attribution-NonCommercial 4.0 International License (http://creativecommons.org/licenses/by-nc/4.0/), which permits any noncommercial use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license and indicate if changes were made.

Cite this article

TY  - CONF
AU  - Minyan Li
AU  - Jianchao Wang
AU  - Qian Zhang
AU  - Deyin Huang
PY  - 2023
DA  - 2023/07/21
TI  - Chlorine Poisoning Risk Management Based on ALOHA Simulation
BT  - Proceedings of the 10th Annual Meeting of Risk Analysis Council of China Association for Disaster Prevention (RAC 2022)
PB  - Atlantis Press
SP  - 337
EP  - 342
SN  - 2352-5428
UR  - https://doi.org/10.2991/978-94-6463-194-4_47
DO  - 10.2991/978-94-6463-194-4_47
ID  - Li2023
ER  -