Proceedings of the 2015 International Symposium on Energy Science and Chemical Engineering

One-Pot Reaction for Synthesis of 1,2,3-Triazole Thioethers from Iodotriazole, Sulfur and Alkylhalides/Tosylates

Authors
Bei Yang, Yining Wen, Zhen Jiang, Linlin Zhang, Pan Yu, Ningning Liu, Jian Zhang, Qinpei Wu
Corresponding Author
Bei Yang
Available Online December 2015.
DOI
10.2991/isesce-15.2015.42How to use a DOI?
Keywords
Triazole, Thioether, Copper, Halide, Tosylate, Reduction
Abstract

A tandem procedure catalyzed by CuI has been developed for the synthesis of 1,2,3-triazole thioethers. Treatment of iodo 1,2,3-triazole with sulfur and followed by reduction with NaBH4 and alkylation with alkylhalides or tosylates in one–pot forms various triazole thioethers under mild conditions. This sequential reaction exhibits remarkable features, such as efficiency, broad substrate scope, good functional group tolerance and easy operation.

Copyright
© 2015, the Authors. Published by Atlantis Press.
Open Access
This is an open access article distributed under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).

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Volume Title
Proceedings of the 2015 International Symposium on Energy Science and Chemical Engineering
Series
Advances in Engineering Research
Publication Date
December 2015
ISBN
10.2991/isesce-15.2015.42
ISSN
2352-5401
DOI
10.2991/isesce-15.2015.42How to use a DOI?
Copyright
© 2015, the Authors. Published by Atlantis Press.
Open Access
This is an open access article distributed under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).

Cite this article

TY  - CONF
AU  - Bei Yang
AU  - Yining Wen
AU  - Zhen Jiang
AU  - Linlin Zhang
AU  - Pan Yu
AU  - Ningning Liu
AU  - Jian Zhang
AU  - Qinpei Wu
PY  - 2015/12
DA  - 2015/12
TI  - One-Pot Reaction for Synthesis of 1,2,3-Triazole Thioethers from Iodotriazole, Sulfur and Alkylhalides/Tosylates
BT  - Proceedings of the 2015 International Symposium on Energy Science and Chemical Engineering
PB  - Atlantis Press
SP  - 212
EP  - 215
SN  - 2352-5401
UR  - https://doi.org/10.2991/isesce-15.2015.42
DO  - 10.2991/isesce-15.2015.42
ID  - Yang2015/12
ER  -