Catalytic activity of metal acetate in transesterification of diphenyl carbonate and 1,4-butyldiol

DOI

10.2991/ic3me-15.2015.71How to use a DOI?

Keywords

Polycarbonate diols; Diphenyl caebonate; 1,4-Butyldiol; Metal acetate; transesterification

Abstract

Synthesis of polycarbonate diols from diphenyl carbonate and 1,4-butyl diol has been demonstrated in the presence of metal acetate catalysts. Alkali metal acetate and alkaline earth metal acetate catalysts showed much higher catalytic activity, of them, lithium acetate was the most active. And the catalytic mechanism was discussed.

Copyright

© 2015, the Authors. Published by Atlantis Press.

Open Access

This is an open access article distributed under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).

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TY  - CONF
AU  - Liping Wang
AU  - Shuihua Zhang
AU  - Xiaolin Xu
PY  - 2015/08
DA  - 2015/08
TI  - Catalytic activity of metal acetate in transesterification of diphenyl carbonate and 1,4-butyldiol
BT  - Proceedings of the 3rd International Conference on Material, Mechanical and Manufacturing Engineering
PB  - Atlantis Press
SP  - 367
EP  - 370
SN  - 2352-5401
UR  - https://doi.org/10.2991/ic3me-15.2015.71
DO  - 10.2991/ic3me-15.2015.71
ID  - Wang2015/08
ER  -