Synthesis and Photochromism Studies of 1-[2-methyl-5-(2-pyridyl)-3-thienyl]-2-[2-methyl-5-(4-bromomethylphenyl)-3-thienyl] Perfluorocyclopentene
Authors
X.G. Tang, H.L. Liu, S.Z. Pu
Corresponding Author
X.G. Tang
Available Online March 2016.
- DOI
- 10.2991/meep-15.2016.19How to use a DOI?
- Keywords
- diarylethene; photochromism; zeroth/first reaction; concentration
- Abstract
A new photochchromic diarylethene was synthesized and explored, which is named 1-[2-methyl-5-(2- pyridyl)-3thienyl]-2-[2-methyl-5- 4-bromomethylphenyl -3- thienyl]perfluorocyclopentene. The results showed that it have excellent photochromism, accompanied with the color change from colorless to blue, by photoirradiation in acetonitrile. When irradiated with UV light, the absorbance at 298 nm decreased, while the absorption at 598 nm increased significantly in acetonitrile. In acetonirile, the kinetic experiments showed that the cyclization/cycloreversion process of 1O was determined to be the zeroth/first reaction.
- Copyright
- © 2016, the Authors. Published by Atlantis Press.
- Open Access
- This is an open access article distributed under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).
Cite this article
TY - CONF AU - X.G. Tang AU - H.L. Liu AU - S.Z. Pu PY - 2016/03 DA - 2016/03 TI - Synthesis and Photochromism Studies of 1-[2-methyl-5-(2-pyridyl)-3-thienyl]-2-[2-methyl-5-(4-bromomethylphenyl)-3-thienyl] Perfluorocyclopentene BT - Proceedings of the 2015 International Conference on Materials Chemistry and Environmental Protection (meep-15) PB - Atlantis Press SP - 69 EP - 71 SN - 2352-541X UR - https://doi.org/10.2991/meep-15.2016.19 DO - 10.2991/meep-15.2016.19 ID - Tang2016/03 ER -