Comprehensive Study on the Structural, Electrical, and Thermistor Behaviour of Sodium Manganese Titanium Tungstate Ceramic
- DOI
- 10.2991/978-94-6239-727-9_2How to use a DOI?
- Keywords
- Double Perovskite; XRD; Dielectric; Impedance; Thermistor
- Abstract
A mixed B-site double perovskite ceramic, Na2(Mn0.5Ti0.5)WO6, was synthesised via a conventional solid-state route and comprehensively examined for its structural, microstructural, dielectric, impedance, and thermistor properties. X-ray diffraction analysis confirmed that the ceramic exhibits a dual-phase crystal structure. FESEM imaging revealed densely packed agglomerated grains with an average size of ~220 nm, while EDX confirmed the homogeneous distribution of Na, Mn, Ti, W, and O without extraneous impurities. Dielectric studies showed strong frequency-dependent dispersion and an increase in permittivity with temperature, attributed to Maxwell–Wagner interfacial polarisation and thermally activated defect dynamics. Impedance spectroscopy demonstrated non-Debye relaxation and revealed that the grain- and grain-boundary-related contributions evolve with temperature, consistent with a transition from (CQR) to (CQR)(CR) circuit behaviour. Measurements of resistance that depend on temperature showed a clear negative-temperature-coefficient (NTC) thermistor response that was caused by small-polaron hopping and conduction through oxygen vacancies. The results taken together show that the ceramic is a good choice for use in electronics and high-temperature sensing.
- Copyright
- © 2026 The Author(s)
- Open Access
- Open Access This chapter is licensed under the terms of the Creative Commons Attribution-NonCommercial 4.0 International License (http://creativecommons.org/licenses/by-nc/4.0/), which permits any noncommercial use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license and indicate if changes were made.
Cite this article
TY - CONF AU - S. B. Bhoobash AU - M. Suman Kalyan AU - C. Behera PY - 2026 DA - 2026/07/22 TI - Comprehensive Study on the Structural, Electrical, and Thermistor Behaviour of Sodium Manganese Titanium Tungstate Ceramic BT - Proceedings of the International Conference on Sustainable Micro-Nano Materials & Innovative Technology (ICSUMMIT 2026) PB - Atlantis Press SP - 7 EP - 18 SN - 2589-4943 UR - https://doi.org/10.2991/978-94-6239-727-9_2 DO - 10.2991/978-94-6239-727-9_2 ID - Bhoobash2026 ER -