Synthesis and Crystal Structures of a mixed-metal Complex with Nitrilotriacetamides

DOI

10.2991/icmse-17.2017.44How to use a DOI?

Keywords

crystal structure, nitrilotriacetamide, mixed-metal complex

Abstract

A novel complex with nitrilotriacetamides(L) has been synthesized. Single-crystal X-ray diffraction analysis determined the molecular formula as C12H28N8Na2NiO10. The crystal belongs to the triclinic system with P-1 space group. In this molecule, the L ion exhibits an infrequent coordination mode. The nickel center is hexa-coordinated to a slightly distorted octahedral configuration by six nitrogen atoms from two L ligands. The sodium ion is six-coordinated with three oxygen atoms of ligands and three oxygen atoms of water molecules. Two water molecules bridge two Na+ ions.

Copyright

© 2017, the Authors. Published by Atlantis Press.

Open Access

This is an open access article distributed under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).

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TY  - CONF
AU  - Guichun Sun
AU  - Jingwen Ran
PY  - 2017/04
DA  - 2017/04
TI  - Synthesis and Crystal Structures of a mixed-metal Complex with Nitrilotriacetamides
BT  - Proceedings of the 2017 7th International Conference on Manufacturing Science and Engineering (ICMSE 2017)
PB  - Atlantis Press
SP  - 245
EP  - 249
SN  - 2352-5401
UR  - https://doi.org/10.2991/icmse-17.2017.44
DO  - 10.2991/icmse-17.2017.44
ID  - Sun2017/04
ER  -