Tetra-cobalt-substiituted Dimeric Tungstoantimonate: Na10[Co4(H2O)10(B- -SbW9O33)2]•36H2O
- 10.2991/icaemt-15.2015.133How to use a DOI?
- Polyoxometalate (POM), Cobalt, Substitute
A new tetra-cobalt-substiituted dimeric tungstoantimonate Na10[Co4(H2O)10(B- -SbW9- O33)2]•36H2O 1 was synthesized in a weakly alkaline solution. The compound was characterized by elemental analysis and IR spectroscopy. A single-crystal X-ray analysis was carried out on the crystal 1 which crystallizes in monoclinic system, space group P 21/n, with a = 12.529 Å, b = 12.778 Å, c = 29.434 Å, = 90.000º, = 101.158º , = 90.000º and Z = 2. Polyanion 1 consists of two B- -SbW9 units which are linked by four cobalt ions leading to a Keggin-type tetra-cobalt-substiituted dimeric structure.
- © 2015, the Authors. Published by Atlantis Press.
- Open Access
- This is an open access article distributed under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).
Cite this article
TY - CONF AU - Rongxin Tan AU - Tongxin Xiao AU - Jin Wang AU - Pingping Zhao PY - 2015/08 DA - 2015/08 TI - Tetra-cobalt-substiituted Dimeric Tungstoantimonate: Na10[Co4(H2O)10(B- -SbW9O33)2]•36H2O BT - Proceedings of the 2015 International Conference on Advanced Engineering Materials and Technology PB - Atlantis Press SP - 700 EP - 703 SN - 2352-5401 UR - https://doi.org/10.2991/icaemt-15.2015.133 DO - 10.2991/icaemt-15.2015.133 ID - Tan2015/08 ER -