Proceedings of the 2015 Asia-Pacific Energy Equipment Engineering Research Conference

Mn-, Ru-Coordinated Covalent Triazine Framework as Catalysts for Epoxidation of Cyclohexene

Authors
Xue Liu, Ling Zhang, Wei-Qiao Deng, Nian-Yu Huang
Corresponding Author
Xue Liu
Available Online June 2015.
DOI
10.2991/ap3er-15.2015.26How to use a DOI?
Keywords
Covalent triazine framework; polymerization; cyclohexene epoxidation; catalysis; coordination
Abstract

The alkene epoxidation is an important reaction for organic synthesis and the catalytic epoxidation of cyclohexene can be widely used for the synthesis of fine chemicals. In this work, a new kind of heterogeneous catalysts, Mn/Ru coorindated covalent triazine framework (Mn-CTF and Ru-CTF), for oxidation of cyclohexene to epoxy hexane were designed. The catalyst Mn-CTF/Ru-CTF was prepared via coordination of manganese chloride hydrate/ruthenium trichloride (III) hydrate with CTF, which was obtained by self-polymerization of 2, 6-pyridinedicarbonitrile. Reducing and oxidizing agents are isobutyraldehyde and molecular oxygen. The yield of epoxidation reaction of cyclohexene catalyzed by the Mn-CTF and Ru-CTF can be up to 97% and 99% under room temperature and atmospheric pressure, respectively.

Copyright
© 2015, the Authors. Published by Atlantis Press.
Open Access
This is an open access article distributed under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).

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Volume Title
Proceedings of the 2015 Asia-Pacific Energy Equipment Engineering Research Conference
Series
Advances in Engineering Research
Publication Date
June 2015
ISBN
978-94-62520-63-9
ISSN
2352-5401
DOI
10.2991/ap3er-15.2015.26How to use a DOI?
Copyright
© 2015, the Authors. Published by Atlantis Press.
Open Access
This is an open access article distributed under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).

Cite this article

TY  - CONF
AU  - Xue Liu
AU  - Ling Zhang
AU  - Wei-Qiao Deng
AU  - Nian-Yu Huang
PY  - 2015/06
DA  - 2015/06
TI  - Mn-, Ru-Coordinated Covalent Triazine Framework as Catalysts for Epoxidation of Cyclohexene
BT  - Proceedings of the 2015 Asia-Pacific Energy Equipment Engineering Research Conference
PB  - Atlantis Press
SP  - 107
EP  - 110
SN  - 2352-5401
UR  - https://doi.org/10.2991/ap3er-15.2015.26
DO  - 10.2991/ap3er-15.2015.26
ID  - Liu2015/06
ER  -